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Fig. 4 Time course of the nano-Pd@PfFerritin-catalysed oxidation of
4
4
-methoxybenzyl alcohol. Conditions: [4-methoxybenzyl alcohol] =
0 mM, [nano-Pd@PfFerritin] = 1.3 mM in water (unbuffered),
p = 30 bar (of a O
representative reaction, (
benzaldehyde.
2
/N
2
8 : 92 mixture), (’) time course of a
}
) time course in the presence of 40 mM
In conclusion, we have prepared a well-defined novel metal–
protein hybrid catalyst using the ferritin cage from P. furiosus.
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alternative to the commonly used mesophilic analogs due to
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This project was financially supported by the Dutch Ministry
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