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converted into concentration by taking into account the
dilution. The kinetics were also studied under pseudo-first-
order conditions with a sufficiently large excess concentra-
tionofcrotylalcohol(CrA)overthatofhexacyanoferrate(III)
[HCF (III)]. Pseudo-first-order plots were made and the
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Stoichiometry and product analysis
The stoichiometry of the reaction was determined by taking
excess [HCF(III)] with respect to that of [CrA] keeping
[OH−] at 0.05 mol dm−3, [EDTA] = 0.01 mol dm−3 and
[Os(VIII)] = 1 × 10−6 mol dm−3, allowing them to react in
a thermostated water bath at 45°C ± 0.1°C for ca. 6 h. The
excess hexacyanoferrate(III), after completion of the reac-
tion, was determined spectrophotometrically. These stoi-
chiometric results correspond to the reaction of two moles
of hexacyanoferrate(III) with one mole of crotyl alcohol as
represented by equation (13).
3−
2 Fe CN
+ CH3 − CH = CH − CH2 − OH
(
)
6
4−
O (VIII)
13
−
S
+ 2OH →2 Fe CN
+
(
)
6
CH3 − CH = CH − CHO + 2H2O
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The oxidation product of the alcohol, crotonaldehyde
was tested positive using Tollen’s reagent. The product was
also identified and established spectroscopically by prepar-
ing the 2,4-dinitrophenyl hydrazone derivative of the oxi-
dation product.
Acknowledgements
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1998; 15: 75.
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4(3): 290.
Acknowledgement is made to the co-authors and Head of
Department of Chemistry, UOR, Jaipur, Rajasthan, India. Authors
also want to dedicate this work to Prof. (Late) P. D. Sharma,
Department of Chemistry, UOR, Jaipur, Rajasthan, India.
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Declaration of conflicting interests
The author(s) declared no potential conflicts of interest with
respect to the research, authorship, and/or publication of this
article.
Funding
34. Sharma P, Sailani R, Meena A, et al. Int J Chem Kint 2018;
50: 335.
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2008; 9: 1389.
36. Davies LJ, Mcmorn P, Bethell D, et al. J Mol Catal (A) 2001;
165: 243.
The author(s) disclosed receipt of the following financial support
for the research, authorship, and/or publication of this article: This
work was financially supported in part by the University Grant
Commission, New Delhi, India through a start-up grant (BSR).
37. Friedrich HB and Singh N. Tetrahedron Lett 2000; 41: 3971.
38. Lee AF, Chang Z, Ellis P, et al. J Phy Chem (C) 2007; 111:
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ORCID iD
Riya Sailani
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