Rhodium-catalyzed asymmetric 1,4-addition of 2-alkenyl-1,3,2- benzodioxaboroles to α,β-unsaturated ketones

DOI: 10.1016/S0040-4039(98)01866-8

Source and publish data:

Tetrahedron Letters p. 8479 - 8482 (1998)

Update date:2022-08-17

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Authors:

Takaya, Yoshiaki

Ogasawara, Masamichi

Hayashi, Tamio

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Article abstract of DOI:10.1016/S0040-4039(98)01866-8

Reaction of 2-alkenyl-1,3,2-benzodioxaboroles, which are readily accessible by hydroboration of alkynes with catecholborane, with α,β- unsaturated ketones in the presence of rhodium/(S)-binap catalyst and triethylamine in dioxane/H₂O (10/1) pro

Full text of DOI:10.1016/S0040-4039(98)01866-8

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