Tetrahedron Letters p. 31 - 34 (1998)
Update date:2022-08-26
Topics:
Zhu, Yao-Hua
Vogel, Pierre
Nucleophilic additions to D-isolevoglucosenone are face selective and generate the corresponding enolates which react with 1.2:3,4-di-O- isopropylidene-α-D-galacto-hexodialdo-1,5-pyranose to give aldol adducts. These can be reduced stereoselectively into C(1→3) glycosides of 1,6- anhydro-D-galacto-pyranose.
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Doi:10.1021/acs.jnatprod.6b00510
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