Materials Research Bulletin p. 1045 - 1052 (1988)
Update date:2022-08-17
Topics:
Toshev, A.
Peshev, P.
On the basis of thermodynamic analysis of reactions with the participation of elemental halogens and halogen-containing compounds, it was established that chlorine and especially carbon tetrachloride are suitable agents for the chemical transport of tin dioxide. The results of thermodynamic analysis are confirmed by experiments on SnO2 single-crystal growth. In the presence of CCl4, well-shaped cassiterite crystals with a maximum size of about 3 mm are obtained. Their light yellow color shows a deviation from the stoichiometric composition.
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