Derivatives of Tris(2,2'-bipyridine)ruthenium(II) with Pendant Pyridyl or Phenol Ligands

DOI: 10.1039/DT9920000703

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 703 - 708 (1992)

Update date:2022-08-10

Topics:

Authors:

Hayes, Martin A.

Meckel, Claudia

Schatz, Erik

Ward, Michael D.

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Article abstract of DOI:10.1039/DT9920000703

Reaction of 2,2':4',4''-terpyridine or 4-(4-pyridyl)-2,2':4',4''-terpyridine with (bipy = 2,2'-bipyridine) and of 4-(p-methoxyphenyl)-2,2'-bipyridine with followed by demethylation of the anisole with BBr3, yields derivatives of Ru(bipy)3(2+) which contain externally directed pendant pyridyl or phenol groups capable of ligation to other metals.These complexes are proposed as 'building blocks' for photoactive polynuclear complexes containing the Ru(bipy)3(2+) chromophore.Methylation of the pendant pyridyl rings with methyl iodide generates electron-accepting groups covalently attached to the Ru(bipy)3(2+) core.

Full text of DOI:10.1039/DT9920000703

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