Organic and Biomolecular Chemistry p. 355 - 360 (2012)
Update date:2022-08-10
Topics:
Khiar, Noureddine
Leal, Manuel Pernia
Navas, Raquel
Moya, Juan Francisco
Perez, Maria Victoria Garcia
Fernandez, Inmaculada
Reported is the synthesis of a number of diastereomerically pure cationic Rh(i)-complexes I starting from phosphinite thioglycosides. These complexes were used in the asymmetric hydrosilylation of prochiral ketones. The reactivity and enantioselectivity o
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