Journal of the American Chemical Society
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catalyst was achieved. This lower activity is partly attributed to
the different weak interactions between the guest and pore-wall
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molecules and to the potential pore blockage in NiTCPE2 by
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carbonaceous material formed during the reaction.
These re-
sults manifest that the size of the channels is an important factor
that controls the efficiency of the conversion by influencing the
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38
transport of the substrates and products through the channels.
7
In conclusion, a new material comprised discrete single-
walled metal-organic nanotube was synthesized by incorporating
the tetraphenylethylene moiety as the backbone, and subsequently
used as a heterogeneous catalyst for the cycloaddition of carbon
dioxide to epoxides. This material represents the largest cross
section of the reported single-walled metal-organic nanotubes. It
features the strong stability and highest activity with a turnover
number reach to 35,000 per mole of catalyst after 20 times (70
hours) repeating reactions, further indicating the broad prospects
of the nanotubes for the practical application in the chemical in-
dustry for the carbon dioxide cycloaddition to cyclic carbonates.
Control experiments based on the 3D framework revealed the
superiority of the large cross-section of the nanotubes. The excel-
lent catalytic activity and better stability suggest that the new ap-
proach for the construction of metal-organic nanotubes as efficient
heterogeneous catalysts is promising.
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ASSOCIATED CONTENT
Supporting Information
(21) Shin, S. M.; Lee, M. S.; Han, J. H.; Jeong, N. Chem. Commun. 2014,
0, 289–291.
Crystal data (CIF file), experimental details and additional
catalytic information. This material is available free of charge
via the Internet at http://pubs.acs.org.
5
(22) Sumida, K.; Rogow, D. L.; Mason, J. A.; McDonald, T. M.; Bloch,
E. D.; Herm, Z. R.; Bae, T. H.; Long, J. R. Chem. Rev. 2012, 112,
7
24–781.
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(
23) Zhang, Y. G.; Lim, D. S. W. ChemSusChem 2015, 8, 2606 – 2608.
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mun. 2013, 4: 1960.
AUTHOR INFORMATION
Corresponding Author
(25) Chisholm, M. H.; Zhou, Z. P. J. Am. Chem. Soc. 2004, 126, 11030–
11039.
(26) Martín, C.; Fiorani, G.; Kleij, A. W. ACS Catal. 2015, 5, 1353–
Notes
1
370.
(27) Guillerm, V.; Weseliński, Ł. J.; Belmabkhout, Y.; Cairns, A. J.;
D’Elia, V.; Wojtas, Ł.; Adil, K.; Eddaoudi, M. Nature Chem. 2014,
The authors declare no competing financial interest.
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, 673–680.
ACKNOWLEDGMENTS
(28) Kathalikkattil, A. C.; Kim, D. W.; Tharun, J.; Soek, H. G.; Roshan,
R.; Park, D. W. Green Chem. 2014, 16, 1607–1616.
The work was support by the National Nature Science Foundation
of China (Nos. 21531001 and 21421005) and the Program for
Changjiang Scholars and Innovative Research Team in University
(
29) Gao, W. Y.; Chen, Y.; Niu, Y. H.; Williams, K.; Cash, L.; Perez, P.
J.; Wojtas, L.; Cai, J. F.; Chen, Y. S.; Ma, S. Q. Angew. Chem., Int.
Ed. 2014, 53, 2615–2619.
(
IRT1213).
(30) Beyzavi, M. H.; Klet, R. C.; Tussupbayev, S.; Borycz, J.; Ver-
meulen, N. A.; Cramer, C. J; Stoddart, J. F.; Hupp, J. T.; Farha, O.
K. J. Am. Chem. Soc. 2014, 136, 15861–15864.
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