Organometallics p. 5486 - 5487 (1995)
Update date:2022-08-17
Topics:
Nishibayashi, Yoshiaki
Segawa, Kyohei
Ohe, Kouichi
Uemura, Sakae
A new type of chiral oxazolinylferrocene - phosphine hybrid is a very effective ligand for Rh(I)-catalyzed asymmetric hydrosilylation of simple ketones to give the corresponding sec-alcohols (91% ee) after acid hydrolysis. Similar reactions also proceed highly selectively (96% ee) by use of Ir(I) catalyst, but the configuration of the products is completely reverse.
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Doi:10.1021/j100277a018
(1986)Doi:10.1039/c2cc37190a
(2012)Doi:10.1039/c5nj01728a
(2015)Doi:10.1016/S0040-4039(00)73419-8
(1994)Doi:10.1039/C9CC00283A
(2019)Doi:10.1002/cssc.201500462
(2015)
