Chemistry Letters p. 1103 - 1106 (1985)
Update date:2022-08-25
Topics:
Tomioka, Hideo
Tabayashi, Kazuo
Izawa, Yasuji
The carbene generated by photolysis of sodium α-diazoacetate in a binary mixture of methanol and 2-methyl-2-butene showed 3000 times enhanced reactivity toward methanol relative to the alkene compared to that derived from the corresponding ester or acid.The results are interpreted as indicating that the neighboring carboxylate group interacts with electron-deficient center of carbene.
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