Bulletin of the Chemical Society of Japan p. 2024 - 2026 (1991)
Update date:2022-08-17
Topics:
Wakui, Yoshita
Imura, Hisanori
Suzuki, Nobuo
The partition coefficients of 21H,23H-porphine (H2Por) and its copper(II) (Cu(por)) and zinc(II) (Zn(por)) complexes were determined in nonaqueous two-phase systems.A linear free-energy relationship was observed between the partition coefficients of H2por and Cu(por).The partition coefficient of Zn(por) was suppressed by coordination bonding with the polar solvent molecules.
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