Partition Coefficient of 21H,23H-Porphine and Its Metal(II) Complexes between Heptane and Nonaqueous Polar Solvents

DOI: 10.1246/bcsj.64.2024

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2024 - 2026 (1991)

Update date:2022-08-17

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Authors:

Wakui, Yoshita

Imura, Hisanori

Suzuki, Nobuo

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Article abstract of DOI:10.1246/bcsj.64.2024

The partition coefficients of 21H,23H-porphine (H2Por) and its copper(II) (Cu(por)) and zinc(II) (Zn(por)) complexes were determined in nonaqueous two-phase systems.A linear free-energy relationship was observed between the partition coefficients of H2por and Cu(por).The partition coefficient of Zn(por) was suppressed by coordination bonding with the polar solvent molecules.

Full text of DOI:10.1246/bcsj.64.2024

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