Acta Crystallographica, Section C: Crystal Structure Communications p. 2350 - 2352 (1995)
Update date:2022-08-10
Topics:
Liu, Xiao-Lan
Zhou, You
Li, Wei-Zhong
Fan, Zhi
Miao, Fang-Ming
et al.
The title compound, C16H19ClNO3P, is one of a series of α-substituted aminomethyl phosphonates.There are two independent molecules in the asymmetric unit and it each the P atom adopts a tetrahedral configuration.The P=O double-bond length and the mean P-O single-bond length are 1.425(5) and 1.560(5) Angstroem for molecule (1) and 1.417(6) and 1.562(5) Angstroem for molecule (2), respectively.The P=O double-bond lengths in both molecules are shorter than those in 1,3,2-oxazaphospholidine derivatives and caged bicyclic phosphorus compounds.
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