Journal of Solid State Chemistry p. 49 - 57 (1985)
Update date:2022-08-11
Topics:
Malecki
Tareen
Doumerc
Rabardel
Launay
Kinetics of thermal decomposition in vacuum of Co//3O//4 powder as well as single crystals has been investigated. Discrepancies with the results of previous authors have been discussed. Decomposition of Co//3O//4 proceeds through formation of a compact layer of CoO and hence diffusion is the rate-limiting factor. THe experimental curves alpha (t) can be described for 0. 05 less than alpha less than 0. 85 using a modified Ginstling-Brounshtein equation: 1 minus 2 alpha /3 minus (1 minus alpha )**2**/**3 equals kt**n where the activation energy varies with the degree of decomposition.
Hebei Kangtai Pharmaceutical Co.,Ltd
Contact:+86-0317-3512963
Address:Wugang Road,Mengcun of Cangzhou City,Hebei Province ,China
Huangshan Violet Biological Technology Co., Ltd
Contact:+86-559-2335676
Address:16-201 JinShanYuan,JiangNan New City,TunXi District,HuangShan City,AnHui Province,China
Changzhou Ruiping Chemical Co., Ltd
website:http://www.wishchem.com
Contact:+86-519-82324280
Address:No.288-1 Huacheng Road, Jintan
Xinjiang Zhongtai Chemical Co., Ltd.
Contact:+86-991-8788172
Address:NO.78 XISHAN RD.URUMQI，CHINA
Contact:+8613400661290
Address:No 908,Kangwan Rd, Liuyang Economic
Doi:10.1021/ja972869w
(1998)Doi:10.1016/S0040-4039(02)02845-9
(2003)Doi:10.1016/j.jphotochem.2019.112340
(2020)Doi:10.1016/j.tetlet.2021.152840
(2021)Doi:10.1016/S0040-4039(98)02348-X
(1999)Doi:10.1021/acs.organomet.7b00368
(2017)
