C-C bond activation of cyclopropane ring in hydrosilylation catalyzed by Wilkinson complex

DOI: 10.1016/0040-4039(95)01628-U

Source and publish data:

Tetrahedron Letters p. 7901 - 7904 (1995)

Update date:2022-08-11

Topics:

Authors:

Bessmertnykh, Alla G.

Blinov, Kirill A.

Grishin, Yurii K.

Donskaya, Nadezhda A.

Beletskaya, Irina P.

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Article abstract of DOI:10.1016/0040-4039(95)01628-U

The new synthetic approach to silylated alkenes based on RhCl(PPh₃)₃ catalyzed hydrosilylation of vinylcyclopropanes is proposed. The mechanism of cyclopropane ring opening is discussed.

Full text of DOI:10.1016/0040-4039(95)01628-U

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