Enhancement of Enantiocontrol/Diastereocontrol in Catalytic Intramolecular Cyclopropanation and Carbon-hydrogen Insertion Reactions of Diazoacetates with Rh2(4S-MPPIM)4

DOI: 10.1016/0040-4039(95)01561-U

Source and publish data:

Tetrahedron Letters p. 7579 - 7582 (1995)

Update date:2022-08-10

Topics:

Authors:

Doyle, Michael P.

Zhou, Qi-Lin

Dyatkin, Alexey B.

Ruppar, Daniel A.

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Article abstract of DOI:10.1016/0040-4039(95)01561-U

Dirhodium(II) tetrakis, Rh2(4S-MPPIM)4, provides significant enhancement in enantiocontrol for intramolecular cyclopropanation reactions of allylic diazoacetates and optimal enantiocontrol/diastereocontrol for intramolecular C-H insertion reactions of secondary alkyl diazoacetates.

Full text of DOI:10.1016/0040-4039(95)01561-U

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