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COMMUNICATION
Journal Name
DOI: 10.1039/C9CC04703D
Fig. 3 Schematic illustration during the formation of highly porous α‐Al
2
O
3
powders by the aerosol‐assisted approach with the self‐assembly of asymmetric PS‐b‐PEO
frameworks, with representative TEM images.
copolymer and subsequent thermal crystallization and phase transition of sol‐gel derivative amorphous Al
2
O
3
1
1
1
1
1
1
3 X. Jiang, N. Suzuki, B. P. Bastakoti, K. C.‐W. Wu and Y.
Yamauchi, Chem. Asian. J., 2012, , 1713.
4 S. Dutta, K. C.‐W. Wu and T. Kimura, Chem. Mater., 2015, 27
we deliberate how nanostructure is helpful for obtaining highly
crystallized metal oxide type materials with a retention of
original porous structures, which is a significant insight for the
precise design of advanced nanoporous materials showing high‐
7
,
6
918.
5 Q. Ma, S. Dutta, K. C.‐W. Wu and T. Kimura, Chem. Eur. J.,
10,12,31‐34
performance in various research fields.
Further design
2018, 24, 6886.
6 F. Li, Z. Wang and A. Stein, Angew. Chem. Int. Ed., 2007, 46
,
of nanoporous structure would be possible through controlled
35,36
1885.
preparation of asymmetric block copolymers.
7 F. Li, S. A. Delo and A. Stein, Angew. Chem. Int. Ed., 2007, 46
,
This work was principally conducted as one of the research
projects promoted by “Advanced Research Program for Energy
6
666.
8 J. G. Li and X. Sun, Acta Mater., 2000, 48, 3103.
and Environmental Technologies (FY2017)” by the New Energy 19 J. E. van den Reijen, P. H. Keijzer and P. E. de Jongh,
Materialia, 2018,
0 M. Thommes, K. Kaneko, A. V. Neimark, J. P. Olivier, F.
4, 423.
and Industrial Technology Development Organization (NEDO),
Japan. T.K. also thanks the financial support by JSPS KAKENHI
Grant Number 19H02805.
2
Rodriguez‐Reinoso, J. Rouquerol and K. S. W. Sing, Pure Appl.
Chem., 2015, 87, 1051.
2
1 H. Maruoka, A. Tomita, L. Zheng and T. Kimura, Langmuir,
2
018, 34, 13781.
Conflicts of interest
There are no conflicts to declare.
22 H. Maruoka and T. Kimura, New J. Chem., 2019, 43, 7269.
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3 H. Tian, Z. Lin, F. Xu, J. Zheng, X. Zhuang, Y. Mai and X. Feng,
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