International Journal of Chemical Kinetics p. 282 - 286 (2008)
Update date:2022-08-16
Topics:
Saha, Bidyut
Sarkar, Sucharita
Chowdhury, Kiran M.
Vanadium(V) oxidation of D-glucose shows first-order dependence on D-glucose, vanadium(V), H+, and HSO4-. These observations remain unaltered in the presence of externally added surfactants. The effect of the cationic surfactant (i.e., N-cetylpyridinium chloride [CPC]), anionic surfactant (i.e., sodium dodecyl sulfate [SDS]), and neutral surfactant (i.e., Trion X-100 [TX-100]) has been studied. CPC inhibits the reactions, whereas SDS and TX-100 accelerate the reaction to different extents. Observed effects have been explained by considering the hydrophobic and electrostatic interaction between the surfactants and reactants.
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