Journal of Organic Chemistry p. 1655 - 1656 (1993)
Update date:2022-08-29
Topics:
Menger, F. M.
Mounier, C. E.
Rotation about the R2N-COOR bond in carbamates with three alkyl chains (butyl through octadecyl) was investigated by NMR.Even solvents such as hexadecane and mineral oil did not substantially impede the rotation, revealing a surprising absence of "solvent friction" induced by chain entanglement.Possible explanations at the molecular level and the relevance to membrane systems are discussed.
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