A novel application of the Dess-Martin reagent to the synthesis of an FK506 analogue and other tricarbonyl compounds

DOI: 10.1016/S0040-4039(00)60085-0

Source and publish data:

Tetrahedron Letters p. 167 - 170 (1993)

Update date:2022-08-17

Topics:

Authors:

Batchelor

Gillespie

Golec Golec

Hedgecock

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Article abstract of DOI:10.1016/S0040-4039(00)60085-0

The use of the Dess-Martin reagent for the oxidation of β-hydroxy and β-ketoamides, esters and ketones to the corresponding tricarbonyl compounds is reported. The method is shown to be applicable to the synthesis of analogues of the immunosuppressant FK506.

Full text of DOI:10.1016/S0040-4039(00)60085-0

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