Tetrahedron Letters p. 8487 - 8490 (1997)
Update date:2022-08-30
Topics:
Cole, Thomas E.
Gonzalez, Tomas
The reaction of styrene and 'Cp2Zr' forms the trans-2,5-diphenylzirconacycle. Transmetalation of this zirconacyle with an equivalent of boron trichloride forms the 1-chloro-trans-2,5-diphenylborolane with retention of stereochemistry. This B-chloroborolane is converted into other boranes and can be oxidized to the diol.
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