
Tetrahedron p. 5495 - 5504 (1996)
Update date:2022-08-17
Topics:
Lavastre, Olivier
Ollivier, Laurence
Dixneuf, Pierre H.
Sibandhit, Sourisak
Several poly-ynes X-[C ≡ C-C6H4-](n)C ≡ C-Si(i)Pr3 (X = H, SiMe3) with controlled length (n = 1, 2, 3, 4) have been prepared from the easily accessible 4-trimethylsilylethynyl iodobenzene by using iterative and convergent methods based on both Pd/Cu catalysed C-C cross-coupling and selective desilylation reactions.
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