ChemSusChem
10.1002/cssc.201801560
FULL PAPER
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General procedure for direct esterification of HMF with methanol
catalyzed by AuNPs-sPSB (entry 23, Table 2). A 60 mL stainless steel
pressure reactor, equipped with a magnetic stirring bar, has been
2
012, 77, 259-272.
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[
1
charged with Cs
sieves (50 mg). The reactor has been sealed, pressurized with oxygen at
.5 MPa and depressurized at ambient pressure for five times to
condition the inner atmosphere, charged under oxygen flux with an
anhydrous solution of HMF (16 mg) in methanol (0.5 ml) and DMA (2.0
mL) and finally pressurized with oxygen to 1.5 MPa. The reaction was
run under stirring at 110°C for 16 h. The reactor has been cooled with ice,
the oxygen pressure slowly released and the mixture analysed by 1H-
2
CO
3
(42 mg), AuNPs-sPSB (50 mg) and molecular
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NMR spectroscopy using DMSO-d as solvent and anisole as external
standard. Yields: DMFC 80.2 % and MHMFC 8.6 %.
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2 3
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Acknowledgements
The authors thank Dr. Patrizia Oliva, Dr. Patrizia Iannece and Dr.
Ivano Immediata (Università degli Studi di Salerno) for technical
assistance. Financial support is acknowledged from the
Ministero dell’Istruzione dell’Università e della Ricerca (MIUR,
Roma, Italy, for FARB 2016) and the SPRING cluster
120-126; i) S. E. Davis, L. R. Houk, E. C. Tamargo, A. K. Datye, R. J.
Davis, Catal. Today 2011, 160, 55-60; j) T. Pasini, M. Piccinini, M. Blosi,
R. Bonelli, S. Albonetti, N. Dimitratos, J. A. Lopez-Sanchez, M. Sankar, Q.
He, C. J. Kiely, G. J. Hutchings, F. Cavani, Green Chem. 2011, 13, 2091-
2099; k) O. Casanova, S. Iborra, A. Corma, J. Catal. 2009, 265, 109-116;
l) E. Taarning, I. S. Nielsen, K. Egeblad, R. Madsen, C. H. Christensen,
ChemSusChem 2008, 1, 75-78; m) N. K. Gupta, S. Nishimura, A.
Takagaki, K. Ebitani, Green Chem. 2011, 13, 824-827; n) T. Esben, N. I.
S., E. Kresten, M. Robert, C. C. H., ChemSusChem 2008, 1, 75-78.
(REBIOCHEM research project CTN01_00063_49393). The
Centro di Tecnologie Integrate per la Salute (Project
PONa3_00138) is acknowledged for the 600 MHz NMR and the
MALDI-MS instruments.
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Keywords: gold nanoparticles • oxidation • esterification • HMF •
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