The reaction of diaryl derivatives of bis(triphenylphosphine)platmum(II) with [60]fullerene as a route to the platinum complex η2-C60Pt(PPh3)2

Article abstract of DOI:10.1007/BF02496181

The reaction of cis-Ar₂Pt(PPh₃)₂ (Ar = p-MeC₆H₄ (1a) and Ar = Ph (1b)) with [60]fullerene in toluene afforded the metal-fullerene complex η²-C₆₀Pt(PPh₃)₂ (2), which was isolated in the crystalline state. The reductive elimination between C₆₀ and 1a or 1b also resulted in the formation of biaryls (p-MeC₆H₄)₂ and Ph-Ph. The composition and structure of the compounds were established by ¹H and ³¹P NMR spectroscopy, electronic absorption spectroscopy, and elemental analysis. The homolytic phosphorylation of 2 was additionally studied by the ESR method.

Full text of DOI:10.1007/BF02496181

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Evaluation Only. Created with Aspose.PDF. Copyright 2002-2021 Aspose Pty Ltd.

Evaluation Only. Created with Aspose.PDF. Copyright 2002-2021 Aspose Pty Ltd.