Chemistry Letters p. 159 - 160 (1997)
Update date:2022-08-17
Topics:
Horimoto, Noriko
Mafune, Fumitaka
Kondow, Tamotsu
Chemical reactions of benzotrichloride in an alcohol solution initiated by multiphoton ionization were observed by irradiation of a tightly focused laser beam at wavelength of 274 nm. The product ions ejected from the liquid surface were analyzed by a time-of-flight mass spectrometer. The mass spectra of the ions indicate that alcoholysis occurs between PhCCl+2 produced by multiphoton ionization and alcohol molecules, ROH, giving PhCCl(OR)+ and PhC(OR)+2.
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