Journal of the Chemical Society. Chemical communications p. 1389 - 1391 (1993)
Update date:2022-08-16
Topics:
Chen, Qing-Yun
Duan, Jian-Xing
Methyl 3-oxa-ω-fluorosulfonylperfluoropentanoate FSO2CF2CF2OCF2CO2Me 1, prepared through the reaction of readily available ICF2CF2OCF2CF2SO2F and SO3 followed by MeOH, is a very convenient trifluoromethylating agent; in the presence of copper(I) iodide, 1 not only reacts with vinyl, benzyl allyl, phenyl iodides and bromides, but also with aryl chlorides to give the corresponding trifluoromethyl compounds in moderate to high yield; a probable reaction mechanism is proposed.
View MoreContact:86-516-66656369
Address:The west road of Huaihai, Xuzhou, China
Hangzhou Bayee Chemical Co.,Ltd.
Contact:+86-571-86990109
Address:No.380, Jiangnan Auenue, Binjiang District, Hangzhou, China
Jiangyin Tenghua Import&Export Co.,Ltd.
Contact:+86-510-86263875
Address:Room 402-B,9 Yanling Road, Jiangyin,Jiangsu, China
Tianjin Chemsyntech Chemical Co., Ltd
Contact:+86-22-60872258
Address:Haitai green industry base in Tianjin, K1,5-601
Qingdao Kylin Trading Co., Ltd.
Contact:0086-532-68979884/58972912/68972263/65/88171519
Address:Room 2308,A building International Trade Center No.230 Changjiang Middle Road of Qingdao Economic Development Zone,Shandong,China.
Doi:10.1021/jo00209a033
(1985)Doi:10.1023/A:1014497321272
(2001)Doi:10.1177/1178223420913330
(2020)Doi:10.1134/S1070428016070071
(2016)Doi:10.1002/anie.202013020
(2021)Doi:10.1021/jf60174a047
(1971)
