Journal of the Chemical Society. Chemical communications p. 1389 - 1391 (1993)
Update date:2022-08-16
Topics:
Chen, Qing-Yun
Duan, Jian-Xing
Methyl 3-oxa-ω-fluorosulfonylperfluoropentanoate FSO2CF2CF2OCF2CO2Me 1, prepared through the reaction of readily available ICF2CF2OCF2CF2SO2F and SO3 followed by MeOH, is a very convenient trifluoromethylating agent; in the presence of copper(I) iodide, 1 not only reacts with vinyl, benzyl allyl, phenyl iodides and bromides, but also with aryl chlorides to give the corresponding trifluoromethyl compounds in moderate to high yield; a probable reaction mechanism is proposed.
View MoreNanyang Tianhua pharmaceutical Co.,Ltd.
Contact:+8618639816203
Address:Longsheng Industrial Park
Nanjing Yuance Industry&Trade Co., Ltd.
website:http://www.njyuance.cn/
Contact:+86-25-85439097
Address:B1702, Aoti Bldg, No. 130, Aoti Avenue, Nanjing, China
Hangzhou Gangjin Chemical Co.,Ltd.(expird)
Contact:+86-571-85109780
Address:707 Zhejiang Minhang Bldg., No.290 Zhongshan North Road, Hangzhou 310003, China
Contact:0086-357-6662688
Address:Zhaocheng town, Hongtong County, Linfen City, Shanxi Province
Chongqing Rong＆Quan Pharmaceutical Technology Co. , Ltd.
Contact:86-023-65268721
Address:No. 7, Manshanhong Village, Pingdingshan, Shapingba District, Chongqing Province, China
Doi:10.1021/jo00209a033
(1985)Doi:10.1023/A:1014497321272
(2001)Doi:10.1177/1178223420913330
(2020)Doi:10.1134/S1070428016070071
(2016)Doi:10.1002/anie.202013020
(2021)Doi:10.1021/jf60174a047
(1971)
