A selective synthesis of α-methylene-β-hydroxyalkanones catalyzed by RuH2(PPh3)4

DOI: 10.1016/0022-328X(88)80561-8

Source and publish data:

Journal of Organometallic Chemistry p. C5 - C7 (1988)

Update date:2022-08-22

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Authors:

Matsuda, Isamu

Shibata, Masahiro

Sato, Susumu

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Article abstract of DOI:10.1016/0022-328X(88)80561-8

The RuH2(PPh3)4-catalyzed coupling of vinylketones with aldehydes accomplishes the selective synthesis of α-methylene-β-hydroxyalkanones under neutral conditions.A plausible pathway involving possible intermediacy of a ruthenium enolate is proposed.

Full text of DOI:10.1016/0022-328X(88)80561-8

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