NEW TYPE OF CHARGE-TRANSFER COMPLEXES BETWEEN BENZOIC ACID 2--ETHYL ESTER (TBPE) AND ALIPHATIC AMINES

DOI: 10.1246/cl.1988.1239

Source and publish data:

Chemistry Letters p. 1239 - 1242 (1988)

Update date:2022-08-16

Topics:

Authors:

Nishimura, Norio

Masaki, Kazuko

Miyake, Jun'ichi

Sakai, Tadao

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Article abstract of DOI:10.1246/cl.1988.1239

A study has been made of charge-transfer complexes formed between TBPE and aliphatic amines in nonpolar solvents.Large value of the equilibrium constant, large negative values of the heat of reaction as well as the reaction volume indicate that the complex of this type is very stable and the dative structure through hydrogen bonding is predominant.

Full text of DOI:10.1246/cl.1988.1239

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