Journal of Physical Chemistry p. 1285 - 1286 (1984)
Update date:2022-08-29
Topics:
Jones, Llewellyn H.
Swanson, Basil I.
Ekberg, Scott A.
High-resolution studies of the ν3 mode of UF6 in argon matrices show two dominant sites with a high degree (80percent) of orientational ordering.Upon photolysis UF5 is formed but recombines in part to form UF6 on metastable sites.One site is considerably more amenable to photolysis than the other.On high-temperature annealing (40 K) all the UF5 is converted back to UF6 and the original dominant sites are re-formed to a considerable extent.Through all this photoexcitation, dissociation, recombination, and annealing the original ordering is preserved.
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