Helvetica Chimica Acta p. 1095 - 1103 (1987)
Update date:2022-08-10
Topics:
McWhorter, William W.
Jaun, Bernhard
The photochemical formation of bicyclooctenes 3 from 12,13-didehydrosqualene (1) upon irradiation at wavelengths longer than 290 nm is reported.The same photoreaction is also observed with trienes 7 and 8 which like 1 have a remote double bond two C-atoms removed from the triene system.A configurational assignment for bicyclooctene 10 obtained from 8 and a mechanism for the observed photochemical reaction are proposed.
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