Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 633 - 644 (1989)
Update date:2022-08-29
Topics:
Hutchings, Graham J.
Comninos, Helen
Copperthwaite, Richard G.
Rensburg, Lawrence Jansen van
Hunter, Roger
Themistocleous, Themistoclis
A novel procedure for the removal of carbonaceous deposits from catalysts using nitrous oxide is described.The general applicability of this method is demonstrated for zeolites H-Y and H-ZSM-5, acid treated clinoptilolite and supported tungsten oxyde as catalysts for hex-1-ene cracking and methanol conversion reactions.The method is particularly effective for acid-treated clinoptilolite as this material cannot be successfully reactivated using a standard oxygen method.Additionally with zeolite H-Y the procedure permits total removal of the carbonaceous deposits, which cannot be readily achieved using oxygen.For the catalysts investigated, nitrous oxide exhibited a marked variation in its reactivation activity (acid treated clinoptilolite > H-Y > H-ZSM-5 > 10percent WO3/Al2O3), a feature which is not observed with the standard oxygen reactivation procedure.Studies of N2O decomposition of both coked and uncoked catalysts demonstrate that the main process occuring during N2O reactivation is the direct oxidation of the coke deposit by molecular N2O.The reactivation efficacy observed is expressed in terms of (a) the amount of coke deposited on the catalyst and (b) the structure of coke deposit which has been studied using solid-state 13C magic-angle spinning nuclear magnetic resonance spectroscopy.
View MoreQingdao Pana-Life Biochem Co.,Ltd.
Contact:86-532-87683902
Address:No.967 Dalao Road, Licang Zone, Qingdao City,Shandong, China 266021
Nanjing Samwon International Limited
Contact:+86-25-84873444
Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,
Contact:
Address:
Contact:+86 18616952870
Address:Area
Suzhou GR-chem pharma Technology Co.,Ltd
Contact:+086-512-62867016
Address:#415 chang yang Rd.,SIP China,215026
Doi:10.1002/anie.200290036
(2002)Doi:10.1039/c9cc06829e
(2019)Doi:10.1016/j.bmc.2017.08.029
(2018)Doi:10.1002/cplu.201600064
(2016)Doi:10.1039/c4cc02614d
(2014)Doi:10.1039/c9ob01962f
(2019)
