ADSORPTION AND REACTION OF TRANS-CINNAMONITRILE ON A SILVER SURFACE INVESTIGATED BY RAMAN SPECTROSCOPY

DOI: 10.1016/0022-2860(90)80396-2

Source and publish data:

Journal of Molecular Structure p. 127 - 139 (1990)

Update date:2022-08-28

Topics:

Authors:

Chun, Hyun Aee

Kim, Myung Soo

Kim, Kwan

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Article abstract of DOI:10.1016/0022-2860(90)80396-2

Adsorption of trans-cinnamonitrile on the metal surface in silver sol has been investigated by the surface-enhanced Raman scattering technique.The molecule is found to adsorb on the surface via its nitrogen lone pair electrons.In the absence of coadsorbed chloride ions, the molecule is converted to trans-cinnamic acid by a surface reaction.When a small amount of sample is irradiated with a laser, a surface photoreaction of trans-cinnamonitrile is observed.

Full text of DOI:10.1016/0022-2860(90)80396-2

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