Mechanism of Isomerization of Cyclopropyl Ethers with Zinc Iodide. New Synthetic Route to Optically Active Allyl Alcohols

DOI: 10.1039/c39920000324

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 324 - 325 (1992)

Update date:2022-08-04

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Authors:

Sugimura, Takashi

Futagawa, Tohru

Ryu, Ilhyong

Tai, Akira

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Article abstract of DOI:10.1039/c39920000324

Isomerization of cyclopropyl ethers to allyl ethers in the presence of zinc iodide is confirmed to proceed by a 1,2-hydride shift mechanism by stereochemical and deuterium labelling experiments.

Full text of DOI:10.1039/c39920000324

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