Tetrahedron Letters p. 2323 - 2326 (1992)
Update date:2022-08-25
Topics:
Baumgartner
Pierini
Rossi
The photostimulated reaction of 2-naphthoxide ions 1 with o-dihalobenzenes in liquid ammonia gives the halosubstituted product 4 and the cyclized substituted product 5. This is the first report about the coupling of an aromatic σ radical with an oxygen functionality in the chain propagation cycle of the S(RN)1 mechanism.
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