STREIC EFFECTS ON REACTION RATES II: RATE AND EQUILIBRIUM CONSTANTS FOR OXIDATION OF BICYCLIC ALCOHOLS

DOI: 10.1016/0040-4039(81)80131-1

Source and publish data:

Tetrahedron Letters p. 715 - 718 (1981)

Update date:2022-08-31

Topics:

Authors:

Mueller, Paul

Blanc, Jacky

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Article abstract of DOI:10.1016/0040-4039(81)80131-1

Equilibrium constants for oxidation of a series of bicyclic alcohols with cyclohexanone have been determined under Meerwein-Pondorf conditions.The data provide the thermodynamic background for interpretation of the mechanism of alcohol oxidation and ketone reductions.Free energies of the equilibrium (ΔG_ox) are compared with values calculated by molecular mechanics.

Full text of DOI:10.1016/0040-4039(81)80131-1

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