STREIC EFFECTS ON REACTION RATES II: RATE AND EQUILIBRIUM CONSTANTS FOR OXIDATION OF BICYCLIC ALCOHOLS

DOI: 10.1016/0040-4039(81)80131-1

Source and publish data:

Tetrahedron Letters p. 715 - 718 (1981)

Update date:2022-08-31

Topics:

Authors:

Mueller, Paul

Blanc, Jacky

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(81)80131-1

Equilibrium constants for oxidation of a series of bicyclic alcohols with cyclohexanone have been determined under Meerwein-Pondorf conditions.The data provide the thermodynamic background for interpretation of the mechanism of alcohol oxidation and ketone reductions.Free energies of the equilibrium (ΔG_ox) are compared with values calculated by molecular mechanics.

Full text of DOI:10.1016/0040-4039(81)80131-1

Products guided by the article

Product name:3,3,5,5-TETRAMETHYLCYCLOHEXANONE

Cas No:14376-79-5

R&D Labs maybe for 14376-79-5

PharmaResources(Kaiyuan)CO,.Ltd

Contact:+86-21-50720028

Address:No.3, Beihuan Road, Economic Development District, Kaiyuan City, Tieling City, Liaoning Province, China 112300
Meryer (Shanghai) Chemical Technology Co., Ltd.

website:http://www.meryer.com/cn/index/

Contact:+86-755-86170518

Address:Minhang,Shanghai, China
Nanjing Raise Pharmatech Co., Ltd

website:http://www.raisechem.com

Contact:+86-25-58649566

Address:B381,No.606,Ningliu Road,Jiangbei New Area,Nanjing,Jiangsu Province,China
Changzhou Screw International Trading Co., Ltd.

Contact:13906149256,18001495888

Address:Jiangsu，Jintanqu
Shanghai He Yang International Trading Co., Ltd.

Contact:+86-21-52043598

Address:Room 816, Blag.5, No.58 Huachi Road

Relevant to this article

Diverse copper(iii) trifluoromethyl complexes with mono-, bi- and tridentate ligands and their versatile reactivity

Doi:10.1039/c8dt00291f
(2018)
Estimation of coordination bond energies of NH₃, H₂O and Et₂NH ligands in the Ni(II) and Cu(II) complexes

Doi:10.1007/s10973-009-0176-3
(2009)
Synthesis of new thienylene pyrrole monomers and their electropolymerizations

Doi:10.1149/2.0011414jes
(2014)
One-pot multicomponent synthesis of novel 2-(piperazin-1-yl) quinoxaline and benzimidazole derivatives, using a novel sulfamic acid functionalized Fe₃O₄ MNPs as highly effective nanocatalyst

Doi:10.1002/aoc.6005
(2021)
Exploring the Effects of Glycosylation and Etherification of the Side Chains of the Anticancer Drug Mitoxantrone

Doi:10.1002/cmdc.201500274
(2015)
Oxygenation of Styrene by Cytochrome P-450 Model Systems: A Mechanistic Study

Doi:10.1021/ja00270a016
(1986)

Article Doi