Tetrahedron Letters p. 4369 - 4370 (1982)
Update date:2022-08-16
Topics:
Uemura, Motokazu
Shimada, Katsuhiko
Tokuyama, Takashi
Daly, John W.
The absolute configuration of the diol moiety in the side chain of pumiliotoxin B has been established by comparison of the ozonolysis product from pumiliotoxin B diacetate with the synthetic 3,4-diacetoxy-2-pentanone derived from L-(+)-tartaric acid.This indicates the absolute configuration (R,R) of C-15, C-16 diol of pumiliotoxin B.
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(2015)
