144829-98-1

Basic information

• Product Name: D-threo-2-Pentulose, 1,5-dideoxy-3,4-O-(1-methylethylidene)- (9CI)
• Synonyms: D-threo-2-Pentulose, 1,5-dideoxy-3,4-O-(1-methylethylidene)- (9CI)
• CAS NO: 144829-98-1
• Molecular Formula: C₈H₁₄O₃
• Molecular Weight: 158.19496
• Product Categories: ACETYLGROUP
• Mol File: 144829-98-1.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: D-threo-2-Pentulose, 1,5-dideoxy-3,4-O-(1-methylethylidene)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: D-threo-2-Pentulose, 1,5-dideoxy-3,4-O-(1-methylethylidene)- (9CI)(144829-98-1)
• EPA Substance Registry System: D-threo-2-Pentulose, 1,5-dideoxy-3,4-O-(1-methylethylidene)- (9CI)(144829-98-1)

Safety Data

• Hazardous Substances Data: 144829-98-1(Hazardous Substances Data)

Upstream product

• 91913-82-5 1-((4S,5S)-2,2,5-Trimethyl-[1,3]dioxolan-4-yl)-ethanol 
• 155322-89-7 (4S,5R)-2,2,5-trimethyl[1,3]dioxolane-4-carbonyl chloride 
• 99603-55-1 (4S,5R)-2,2,5-trimethyl-1,3-dioxolane-4-carbaldehyde 
• 107983-40-4 (4R,5S)-2,2,5-trimethyl-1,3-dioxolane-4-carboxylic acid 
• 1336854-12-6 (4R,5S)-N-methoxy-N,2,2,5-tetramethyl-1,3-dioxolane-4-carboxamide 
• 676-58-4 methylmagnesium chloride 
• 1336854-09-1 biphenyl-4-ylmethyl (4R,5S)-2,2,5-trimethyl-1,3-dioxolane-4-carboxylate 
• 84519-53-9 (4R,5S)-2,2,5-trimethyl-1,3-dioxolane-4-carbaldehyde 
• 127062-02-6 (4S,5R)-2,2,5-Trimethyl-[1,3]dioxolane-4-carboxylic acid 
• 38410-80-9 methyl (4S)-trans-2,2,5-trimethyl-1,3-dioxolane-4-carboxylate 
• 75-16-1 methylmagnesium bromide 
• 73711-65-6 (4R,5R)-<5-(hydroxymethyl)-2,2-dimethyl-1,3-dioxolane-4-yl>methyl p-toluenesulfonate 
• 77-76-9 2,2-dimethoxy-propane 

Downstream Products

• 144735-51-3 (2S)-2-<(R)-1-(benzyloxy)-1-<(tert-butyldimethylsiloxy)methyl>ethyl>-N-<(2E,6E)-(4R,8R,9R)-8,9-(isopropylidenedioxy)-4,7-dimethyl-2,6-decadien-1-yl>pyrrolidine 
• 144735-52-4 (2S)-2-<(R)-1-(benzyloxy)-1-formylethyl>-N-<(2E,6E)-(4R,8R,9R)-8,9-(isopropylidenedioxy)-4,7-dimethyl-2,6-decadien-1-yl>pyrrolidine 
• 153108-95-3 (2S)-2-<(R)-1-(benzyloxy)-1-(hydroxymethyl)ethyl>-N-<(2E,6E)-(4R,8R,9R)-8,9-(isopropylidenedioxy)-4,7-dimethyl-2,6-decadien-1-yl>pyrrolidine 
• 144766-10-9 (7R,8R,8aS)-8-(benzyloxy)-7-hydroxy-6(Z)-<6(R),7(R)-(isopropylidenedioxy)-2(R),5-dimethyl-4(E)-octenylidene>-8-methyloctahydroindolizine 
• 153108-96-4 (7R,8R,8aS)-8-(benzyloxy)-7-hydroxy-8-methyl-6-(E)-<(2R,6R,7R)-6,7-dihydroxy-2,5-dimethyl-4-(E)-octenylidene>octahydroindolizidine 
• 155322-90-0 (4S,5R)-5-Acetyl-4-methyl-dihydro-furan-2-one 
• 67016-65-3 Pumiliotoxin B 

Relevant articles and documents

THE ABSOLUTE CONFIGURATION OF THE SIDE CHAIN DIOL MOIETY OF THE POISON-FROG ALKALOID PUMILIOTOXIN B

The absolute configuration of the diol moiety in the side chain of pumiliotoxin B has been established by comparison of the ozonolysis product from pumiliotoxin B diacetate with the synthetic 3,4-diacetoxy-2-pentanone derived from L-(+)-tartaric acid.This indicates the absolute configuration (R,R) of C-15, C-16 diol of pumiliotoxin B.

A convergent total synthesis of pumiliotoxins A and B via palladium-catalyzed cross-coupling reaction of homoallylic organozinc compounds with vinyl iodides

A versatile convergent approach for preparing the pumiliotoxin alkaloids has been developed employing a Pd(0)-catalyzed cross-coupling reaction between homoallylic organozincs and vinyl iodides, which led to the asymmetric total synthesis of (+)-pumilioto

A Selective Baeyer-Villiger Oxidation: A Total Synthesis of (-)-Acetomycin

A short, stereoselective synthesis of (-)-acetomycin (2) from L-threonine is reported.The final step in the synthesis is a selective Baeyer-Villiger oxidation that discriminates between two methyl ketones.