The Tetrahydridosulfonium Dication, H4S2+. Hydrogen-Deuterium Exchange of DH2S+ in FSO3D:SbF5 and D2HS+ in FSO3H:SbF5 and Theoretical Calculations

DOI: 10.1021/j100315a005

Source and publish data:

Journal of Physical Chemistry p. 878 - 880 (1988)

Update date:2022-08-31

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Authors:

Olah, George A.

Prakash, G. K. Surya

Marcelli, Michael

Lammertsma, Koop

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Article abstract of DOI:10.1021/j100315a005

Isotopomeric hydridosulfonium ions undergo proton/deuterium exchange in (Magic Acid) FSO3D*SbF5 and FSO3H-SbF5-SO2 solutions as monitored by 1H NMR spectroscopy.The rate of exchange increases with the increase in acidity of the superacidic medium, indicat

Full text of DOI:10.1021/j100315a005

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