Monatshefte fur Chemie p. 525 - 532 (1988)
Update date:2022-08-16
Topics:
Brunner, Henri
Fisch,Heinrich
The reactivity of several monohydrosilane/complex systems in the hydrosilylation of acetophenone and benzylmethylketone was investigated.The active systems were modified by addition of optically active ligands and used as enantioselective in-situ catalysts for the hydrosilylation of the above prochiral ketones which on hydrolysis gave α-phenylethanol and α-benzylethanol in up to 18percent ee. - Keywords: Monohydrosilanes; Enantioselective hydrosilylation; Prochiral ketones
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