M-(Trimethylsilyldifluoromethyl)-trifluoromethylbenzene

Base Information

• Chemical Name: M-(Trimethylsilyldifluoromethyl)-trifluoromethylbenzene
• CAS No.: 149194-34-3
• Molecular Formula: C11H13 F5 Si
• Molecular Weight: 268.298436
• DSSTox Substance ID: DTXSID10458437
• Mol file: 149194-34-3.mol

Synonyms:149194-34-3;M-(TRIMETHYLSILYLDIFLUOROMETHYL)-TRIFLUOROMETHYLBENZENE;[difluoro-[3-(trifluoromethyl)phenyl]methyl]-trimethylsilane;DTXSID10458437;ZQMNZGHLTTXUEF-UHFFFAOYSA-N;{Difluoro[3-(trifluoromethyl)phenyl]methyl}(trimethyl)silane

Chemical Property of M-(Trimethylsilyldifluoromethyl)-trifluoromethylbenzene

Chemical Property:

• Boiling Point: 197.4±40.0 °C(Predicted)
• PSA: 0.00000
• Density: 1.135±0.06 g/cm3(Predicted)
• LogP: 4.98610
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 2
• Exact Mass: 268.07066776
• Heavy Atom Count: 17
• Complexity: 266

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)C(C1=CC=CC(=C1)C(F)(F)F)(F)F

Technology Process of M-(Trimethylsilyldifluoromethyl)-trifluoromethylbenzene

There total 3 articles about M-(Trimethylsilyldifluoromethyl)-trifluoromethylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1,1,2,2,2-hexamethyldisilane (1450-14-2) + 1,3-bis(trifluoromethyl)benzene (402-31-3) → m-(Trimethylsilyldifluoromethyl)trifluoromethylbenzene (149194-34-3) + (3,5-Bis-trifluoromethyl-phenyl)-trimethyl-silane + (2,4-Bis-trifluoromethyl-phenyl)-trimethyl-silane

Guidance literature:

With phenanthrene; In cyclohexane; Irradiation;

DOI:10.1039/c39930000678

Reference yield:

octamethyltrisilane (3704-44-7) + 1,3-bis(trifluoromethyl)benzene (402-31-3) → m-(Trimethylsilyldifluoromethyl)trifluoromethylbenzene (149194-34-3) + (2,4-Bis-trifluoromethyl-phenyl)-trimethyl-silane + 1-[Difluoro-(3-trifluoromethyl-phenyl)-methyl]-1,1,2,2,2-pentamethyl-disilane

Guidance literature:

In cyclohexane; Irradiation;

DOI:10.1039/c39930000678

Reference yield:

chloro-trimethyl-silane (75-77-4) + 1,3-bis(trifluoromethyl)benzene (402-31-3) → m-(Trimethylsilyldifluoromethyl)trifluoromethylbenzene (149194-34-3) + m-(Bistrimethylsilyldifluoromethyl)trifluoromethylbenzene

Guidance literature:

With tetrabutylammomium bromide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; Further Variations:; various current passed; Product distribution; Electrolysis;

DOI:10.1016/S0022-1139(00)00373-0

upstream raw materials:

1,1,1,2,2,2-hexamethyldisilane

1,3-bis(trifluoromethyl)benzene

octamethyltrisilane

chloro-trimethyl-silane