Synthesis of resorcinols via a Michael addition-Dieckman cyclization sequence of dimethyl 1,3-acetonedicarboxylate anion with alkyl alkynoates

Article abstract of DOI:10.1080/00397919808004454

The reaction of dimethyl 1,3-acetonedicarboxylate anion 1 with a number of alkyl alkynoates gives unsymmetrical (from alkynoates 2a-g) or symmetrical (from alkynoates 2h-i) resorcinols, in a one pot synthesis.

Full text of DOI:10.1080/00397919808004454

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Synthesis of Resorcinols
via a Michael Addition-
Dieckman Cyclization
Sequence of Dimethyl 1,3-
Acetonedicarboxylate Anion
with Alkyl Alkynoates
A. Covarrubias-Zúñiga a , L. A. Maldonado a , E.
Ríos-Barrios a & A. González-Lucas a
a Instituto de Química, Universidad Nacional
Autónoma de México, Circuito Exterior, Ciudad
Universitaria , Coyoacán, 04510, México
Published online: 22 Aug 2006.
To cite this article: A. Covarrubias-Zúñiga , L. A. Maldonado , E. Ríos-Barrios
& A. González-Lucas (1998) Synthesis of Resorcinols via a Michael Addition-
Dieckman Cyclization Sequence of Dimethyl 1,3-Acetonedicarboxylate Anion
with Alkyl Alkynoates, Synthetic Communications: An International Journal for
Rapid Communication of Synthetic Organic Chemistry, 28:18, 3461-3469, DOI:
10.1080/00397919808004454
To link to this article: http://dx.doi.org/10.1080/00397919808004454
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