Journal of Organic Chemistry p. 4042 - 4044 (1987)
Update date:2022-08-22
Topics:
Simon, Ethan S.
Whitesides, George M.
Cameron, Douglas C.
Weitz, David J.
Cooney, Charles L.
Clostridium thermosaccharolyticum (ATCC 31960) converts glucose to (-)-(R)-propylene glycol; standard procedures transform this substance to (+)-(R)-methyloxirane ((+)-(R)-propylene oxide) with enantiomeric excess >99percent.This procedure is capable of generating this useful chiral synthon on a large scale.
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