Tetrahedron p. 6005 - 6016 (1994)
Update date:2022-08-18
Topics:
Katritzky
Katritzky, Alan R.
Ignatchenko
Ignatchenko, Alexey V.
Lan
Lan, Xiangfu
Lang
Lang, Hengyuan
Stevens
Stevens, Christian V.
Opitz
Opitz, Andreas
Koch
Koch, Rainer
Anders
Anders, Ernst
Benzotriazole-assisted β-deprotonation of (α-benzotriazolylvinyl) ethers occurs stereoselectively at the cis position as shown by quenching with a variety of electrophiles. Semiempirical calculations of the lithiated enol ethers by PM3 and MNDO methods disclosed a higher stabilization for the cis-isomers over the corresponding trans-isomers
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