Journal of the Chemical Society. Perkin transactions II p. 1099 - 1104 (1980)
Update date:2022-08-11
Topics:
Norman, Richard O. C.
Thomas, C. Barry
Watson, Grenville
The effects upon product distribution of varying the temperature, time of reaction, and reagent concentrations have been investigated in the oxidation of α-methylstyrene by palladium(II) acetate.Two reaction pathways have been identified.A ?-allylic organopalladium compound decomposes slowly in a process catalysed by excess of the alkene to give 2-phenylprop-2-enyl acetate.The second reaction leads to competitive formation of enolic acetates and oxidative dimers but the organopalladium species involved has not been unambiguously identified.The addition of sodium acetate to the reaction, contrary to earlier reports, has only a marginal effect upon the distribution of products.
View MoreHubei Onward Bio-Development Co., Ltd.
Contact:+86-718-8417012
Address:No.517,Shizhou Avenue,Enshi City,Hubei Province,China,445002
WuHan rongfashun BioChemical co., LTD
Contact:02788866139
Address:No.95 LuoYu Road,Wuhan
Tianjin Realet Chemical Technology Co.,Ltd.
website:http://www.realetchem.com
Contact:+86-022-58788819
Address:shuanggang industrial park
Contact:86-21-57725962
Address:shanghai
Yuan Shi(SuQian)Biotechnology Co.,Ltd
website:http://www.yuanshibio.com
Contact:+86-527-84226672
Address:jiangsu suqian
Doi:10.1021/om050572y
(2005)Doi:10.1039/c39880000841
(1988)Doi:10.1021/bm4010832
(2013)Doi:10.1021/ac901183b
(2009)Doi:10.1080/00397910008087255
(2000)Doi:10.1002/pssa.201026226
(2011)
