An efficient method for N-nitrosation of secondary amines under mild and, heterogeneous conditions

Article abstract of DOI:10.1080/00397910008087255

A combination of inorganic acidic salts or silica gel supported inorganic acids and sodium nitrite in the presence of wet SiO₂ was used as an effective nitrosating agent for the nitrosation of secondary amines to their corresponding nitroso derivatives under mild and heterogeneous conditions in moderate to excellent yields. Mg(HSO₄)₂ and NaHSO₄ are superior to all the aforementioned reagents in convenience, yield and purity of the isolated nitrosoamines.

Full text of DOI:10.1080/00397910008087255

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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An Efficient Method for N-
Nitrosation of Secondary
Amines Under Mild and
Heterogeneous Conditions
Mohammad Ali Zolfigol a , Ezat Ghaemi a , Elahe
Madrakian a & Maryam Kiany-Borazjani a
a Chemistry Department, College of Science, Bu-Ali
Sina University, Hamadan, 65174, Iran E-mail:
Version of record first published: 04 Dec 2007.
To cite this article: Mohammad Ali Zolfigol, Ezat Ghaemi, Elahe Madrakian &
Maryam Kiany-Borazjani (2000): An Efficient Method for N-Nitrosation of Secondary
Amines Under Mild and Heterogeneous Conditions, Synthetic Communications: An
International Journal for Rapid Communication of Synthetic Organic Chemistry, 30:11,
2057-2060
To link to this article: http://dx.doi.org/10.1080/00397910008087255
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