A new etherification reaction in the η4-dienyl-tricarbonyliron series: Access to the 2,5-disubstituted-1,4-dioxane core

Article abstract of DOI:10.1080/00397919508012659

The η4-dienyl tricarbonyliron complex 8 has been used as a valuable building block en route to the 2,5-disubstituted-1,4-dioxane 4. Particularly noteful is the new regioselective etherification reaction of 8 with the suitably protected secondary glycerol 11 through the non-isolated organometallic cation 13.

Full text of DOI:10.1080/00397919508012659

This article was downloaded by: [University of Chicago Library]
On: 22 August 2013, At: 06:40
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954
Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH,
UK
Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/lsyc20
A New Etherification
Reaction in the η4-Dienyl-
Tricarbonyliron Series: Access
to the 2,5-Disubstituted-1,4-
dioxane Core
J. P. Lellouche a & C. Quirosa-Guillou a
a CE- Saclay, Service des Molécules Marquées, Bt
547, 91191, Gif-sur-Yvette Cedex, France
Published online: 23 Sep 2006.
To cite this article: J. P. Lellouche & C. Quirosa-Guillou (1995) A New
Etherification Reaction in the η4-Dienyl-Tricarbonyliron Series: Access to the 2,5-
Disubstituted-1,4-dioxane Core, Synthetic Communications: An International Journal
for Rapid Communication of Synthetic Organic Chemistry, 25:7, 977-993, DOI:
10.1080/00397919508012659
To link to this article: http://dx.doi.org/10.1080/00397919508012659
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the
information (the “Content”) contained in the publications on our platform.
However, Taylor & Francis, our agents, and our licensors make no
representations or warranties whatsoever as to the accuracy, completeness,
or suitability for any purpose of the Content. Any opinions and views

expressed in this publication are the opinions and views of the authors, and
are not the views of or endorsed by Taylor & Francis. The accuracy of the
Content should not be relied upon and should be independently verified with
primary sources of information. Taylor and Francis shall not be liable for any
losses, actions, claims, proceedings, demands, costs, expenses, damages,
and other liabilities whatsoever or howsoever caused arising directly or
indirectly in connection with, in relation to or arising out of the use of the
Content.
This article may be used for research, teaching, and private study purposes.
Any substantial or systematic reproduction, redistribution, reselling, loan,
sub-licensing, systematic supply, or distribution in any form to anyone is
expressly forbidden. Terms & Conditions of access and use can be found at
http://www.tandfonline.com/page/terms-and-conditions