Benzidine Rearrangements. 18. Mechanism of the Acid-Catalyzed Disproportionation of 4,4'-Diiodohydrazobenzene. Application of Heavy-Atom Kinetic Isotope Effects

DOI: 10.1021/ja00347a050

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Journal of the American Chemical Society p. 2823 - 2827 (1983)

Update date:2022-08-11

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Authors:

Shine, Henry J.

Habdas, Jan

Kwart, Harold

Brechbiel, Martin

Horgan, Ann Gafney

Filippo, Joseph San

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Article abstract of DOI:10.1021/ja00347a050

Nitrogen and carbon kinetic isotope effects (KIE) have been measured for the two-proton disproportionation of 4,4'-diiodohydrazobenzene (1).Disproportionation was carried out in 70percent aqueous dioxane under previously described kinetic conditions.The n

Full text of DOI:10.1021/ja00347a050

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