Organic Mass Spectrometry p. 30 - 35 (1987)
Update date:2022-08-17
Topics:
Kingston, Eric E.
Shannon, James S.
Lacey, Michael J.
The skeletal rearrangement for water loss is the dominant reaction in the chemical ioinization mass spectrum of benzyl 2-phenylethyl ether.Isotopic distribution obtained for this reaction with specifically labelled derivates have been interpreted in terms of competing five- and six-centered skeletal rearrangements.Chemical substitution of the altermative aromatic rings strtongly influences the balance of the competition.
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