Tetrahedron Letters p. 429 - 432 (1980)
Update date:2022-08-11
Topics:
Hassner, Alfred
Soderquist, John A.
Pyrolysis and photolysis of the first examples of five-membered ring sila and germa ketones 2 is reported.The photolysis of 2a leading to a cyclic acetal via a siloxycarbene is contrasted to the behavior of the germa analog 2b wich gives ring cleavage via a ketene intermediate.
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