Dicyclohexylborane-catalyzed hydroboration of 1-halo-1-alkynes with 9-borabicyclo[3.3.1]nonane

Article abstract of DOI:10.1080/00397919708003327

A catalytic amount of dicyclohexylborane accelerates the hydroboration of 1-halo-1-alkyne (1) with 9-BBN to provide B-[(Z)-1-halo-1-alkenyl]-9-BBN (2) regio- and stereo-selectively.

Full text of DOI:10.1080/00397919708003327

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Dicyclohexylborane-
Catalyzed Hydroboration
of 1-Halo-1-alkynes with 9-
Borabicyclo[3.3.1]nonane
Masayuki Hoshi a & Akira Arase a
a Department of Applied and Environmental
Chemistry, Kitami Institute of Technology, Koen-
cho, Kitami, 090, Japan
Published online: 20 Aug 2006.
To cite this article: Masayuki Hoshi & Akira Arase (1997) Dicyclohexylborane-
Catalyzed Hydroboration of 1-Halo-1-alkynes with 9-Borabicyclo[3.3.1]nonane,
Synthetic Communications: An International Journal for Rapid Communication of
Synthetic Organic Chemistry, 27:4, 567-572, DOI: 10.1080/00397919708003327
To link to this article: http://dx.doi.org/10.1080/00397919708003327
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