Tetrahedron Letters p. 3209 - 3212 (1987)
Update date:2022-08-29
Topics:
McMurry, John E.
Swenson, Rolf
Titanium-induced cyclization of diketone 4 yields diene 12, presumably by Cope rearrangement of the desired tricyclo<8.21,10.01,7.04,10>-1(7),4(10)-dodecadiene (1).Molecular mechanics calculations support the belief that the rearrangement should be rapid.
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